O,O′-Dimethyl (cyclohexylamido)thiophosphate
نویسندگان
چکیده
The P atom in the title compound, C(8)H(18)NO(2)PS, is bonded in a distorted tetra-hedral PSO(2)N environment with bond angles in the range of 99.23 (5)-115.17 (4)°. The cyclo-hexane ring is disordered over two sets of sites with refined occupancies of 0.528 (5) and 0.472 (5). The ring in both disorder components adopts a chair conformation with the N-H group oriented equatorially. In the crystal, pairs of P=S⋯H-N hydrogen bonds form inversion dimers.
منابع مشابه
N,N-Dibenzyl-O,O′-dimethyl thiophosphate
The P atom in the title compound, C(16)H(20)NO(2)PS, is bonded in a distorted tetra-hedral P(S)(O)(2)N environment with the bond angles at the P atom in the range 99.37 (7) to 115.68 (5)°. The angles at the amido N atom (with bond-angle sum of 357.8°) confirm its sp(2) character. The C-O-P bond angles are 119.78 (11) and 119.39 (12)°.
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